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MilliporeSigma

Diisobutylaluminum hydride solution, 25 wt. % in toluene

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Synonyms: DIBAL; DIBAL-H

CAS Number: 1191-15-7

Formula: C8H19Al

Formula Weight: 142.22

Linear Formula: [(CH3)2CHCH2]2AlH

MDL No.: MFCD00008928

Density: 0.846 g/mL at 25 C

Beilstein Registry Number: 4123663

UNSPSC Code: 12352000

General description: Diisobutylaluminum hydride reducing agent is commonly used for the reduction of an ester to aldehyde.

Application: Diisobutylaluminum hydride solution (25 wt. % in toluene) has been used for the reduction of imides:. N. -(cis-2-Vinylcyclohexyl)succinimide to 1-(cis-2-vinylcyclohexyl)-5-hydroxy-2-pyrrolidinone. N-(But-4-en-1-y1)-2(E)-(carbethoxymethylidene)-5-oxo-pyrrolidine to N-(but-4-en-1-yl)- 2(E)-(carbethoxymethylidene)-5-hydroxypyrrolidine. N-(Hept-1-en-4-y1)-2(E)-(carbethoxymethylidene)-5-oxo-pyrrolidine to N-(hept-1-en-4-y1)-2(E)-(carbethoxymethylidene)-5-hydroxypyrrolidine. N-(cis-2-Vinylcyclohexyl)-2-(carbethoxymethylidene)-5-oxopyrrolidine to rel-(3aR,SS,5aS,SaR)-1( E)-(carbethoxymethylidene)-5-(formyloxy)dodecahydropyrrolo[1,2-a]quinoline

Application: Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

RIDADR: UN 3394 4.3(4.2) / PGI

WGK Germany: 2

Flash Point(F): 39.2 F

Flash Point(C): 4 C

R Codes: 63-11-14/15-17-34-48/20-65-67

S Codes: 16-26-36/37/39-43-45-62

IOD Codes: F,C

Symbol: GHS02, GHS05, GHS07, GHS08

Signal Word: Danger

Hazard Statements: H225-H250-H260-H304-H314-H336-H361d-H373

Precautionary statements: P210-P222-P223-P231 + P232-P370 + P378-P422

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Product Detail
Thomas No.
C984M44
Mfr. No.
192724-100G
Description
Diisobutylaluminum hydride solution, 25wt. % in toluene, 100 g
CAS Number
1191-15-7
Packaging Size
100 g
list price/quantitytotal
$0.00
Thomas No.
C984M45
Mfr. No.
192724-700G
Description
Diisobutylaluminum hydride solution, 25wt. % in toluene, 700 g
CAS Number
1191-15-7
Packaging Size
700 g
list price/quantitytotal
$0.00
$0.00 (0 Items)
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