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Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name SpillSolv ® Multi Purpose Spill Kit Product Code SX1300
Manufacturer
EMD Chemicals Inc.
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
Prior to January 1, 2003 EMD Chemicals Inc. was EM Industries, Inc. or EM Science, Division of EM Industries, Inc.
Effective Date
11/8/2004
For More Information Call In Case of Emergency Call
856-423-6300 Technical Service
Monday-Friday: 8:00 AM - 5:00 PM		 800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Synonym
Acid Spill Kit, SpillSolv ® None.
Caustic Spill Kit, SpillSolv ® None.
Solvent Spill Kit, SpillSolv ® None.
Material Uses
Acid Spill Kit, SpillSolv ® Analytical reagent.
Caustic Spill Kit, SpillSolv ® Analytical reagent.
Solvent Spill Kit, SpillSolv ® Analytical reagent.
Chemical Family
Acid Spill Kit, SpillSolv ® mixture
Caustic Spill Kit, SpillSolv ® mixture
Solvent Spill Kit, SpillSolv ® Carbon

Section 2. Composition and Information on Ingredients
Product name / Reagent. Component ; CAS # ; % by Weight
Acid Spill Kit, SpillSolv ® Sodium Carbonate, Anhydrous; 497-19-8; 60-100%
Caustic Spill Kit, SpillSolv ® Citric Acid, Anhydrous; 77-92-9; 60-100%
Solvent Spill Kit, SpillSolv ® Charcoal; 7440-44-0; 60-100%

Section 3. Hazards Identification
Physical State and Appearance
Acid Spill Kit, SpillSolv ® Solid. (Powder.)
Caustic Spill Kit, SpillSolv ® Solid. (Powder.)
Solvent Spill Kit, SpillSolv ® Solid.
Emergency Overview
Acid Spill Kit, SpillSolv ® CAUTION!
CAUSES SEVERE EYE IRRITATION.
CAUSES RESPIRATORY TRACT AND SKIN IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
Caustic Spill Kit, SpillSolv ® CAUTION!
CAUSES SEVERE EYE IRRITATION.
CAUSES RESPIRATORY TRACT AND SKIN IRRITATION.
Solvent Spill Kit, SpillSolv ® CAUTION!
COMBUSTIBLE SOLID.
MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
Routes of Entry
Acid Spill Kit, SpillSolv ® Inhalation. Ingestion.
Caustic Spill Kit, SpillSolv ® Inhalation. Ingestion.
Solvent Spill Kit, SpillSolv ® Inhalation. Ingestion.
Potential Acute Health Effects
Eyes
Acid Spill Kit, SpillSolv ® Extremely hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching.
Caustic Spill Kit, SpillSolv ® Extremely hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching.
Solvent Spill Kit, SpillSolv ® May be hazardous in case of eye contact (irritant).
Skin
Acid Spill Kit, SpillSolv ® Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Caustic Spill Kit, SpillSolv ® Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Solvent Spill Kit, SpillSolv ® May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Inhalation
Acid Spill Kit, SpillSolv ® Hazardous in case of inhalation (lung irritant).
Caustic Spill Kit, SpillSolv ® Hazardous in case of inhalation (lung irritant).
Solvent Spill Kit, SpillSolv ® May be hazardous in case of inhalation (lung irritant).
Ingestion
Acid Spill Kit, SpillSolv ® May be hazardous in case of ingestion.
Caustic Spill Kit, SpillSolv ® No known acute effects of this product resulting from ingestion.
Solvent Spill Kit, SpillSolv ® No known acute effects of this product resulting from ingestion.
Potential Chronic Health Effects
Carcinogenic Effects
Acid Spill Kit, SpillSolv ® This material is not known to cause cancer in animals or humans.
Caustic Spill Kit, SpillSolv ® This material is not known to cause cancer in animals or humans.
Solvent Spill Kit, SpillSolv ® This material is not known to cause cancer in animals or humans.
Additional information See Toxicological Information (section 11)
Medical Conditions Aggravated by Overexposure:
Acid Spill Kit, SpillSolv ® Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.
Caustic Spill Kit, SpillSolv ® Repeated or prolonged exposure is not known to aggravate medical condition.
Solvent Spill Kit, SpillSolv ® Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4. First Aid Measures
Eye Contact
Acid Spill Kit, SpillSolv ® Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Caustic Spill Kit, SpillSolv ® Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Solvent Spill Kit, SpillSolv ® Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Skin Contact
Acid Spill Kit, SpillSolv ® In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Caustic Spill Kit, SpillSolv ® In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Solvent Spill Kit, SpillSolv ® In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation
Acid Spill Kit, SpillSolv ® If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Caustic Spill Kit, SpillSolv ® If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Solvent Spill Kit, SpillSolv ® If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion
Acid Spill Kit, SpillSolv ® Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Caustic Spill Kit, SpillSolv ® Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Solvent Spill Kit, SpillSolv ® Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 5. Fire Fighting Measures
Flammability of the Product
Acid Spill Kit, SpillSolv ® Non-flammable.
Caustic Spill Kit, SpillSolv ® Non-flammable.
Solvent Spill Kit, SpillSolv ® May be combustible at high temperature.
Auto-ignition Temperature
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Not available.
Flash Points
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Not available.
Flammable Limits
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Not available.
Products of Combustion
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Fire Hazards in Presence of Various Substances
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Slightly flammable to flammable in presence of open flames, sparks and static discharge, of heat.
Explosion Hazards in Presence of Various Substances
Acid Spill Kit, SpillSolv ® Risks of explosion of the product in presence of static discharge: No.

Risks of explosion of the product in presence of mechanical impact: No.
Caustic Spill Kit, SpillSolv ® Risks of explosion of the product in presence of static discharge: No.

Risks of explosion of the product in presence of mechanical impact: No.
Solvent Spill Kit, SpillSolv ® Risks of explosion of the product in presence of static discharge:
Slightly flammable in presence of open flames, sparks and static discharge.
Slightly explosive in presence of open flames, sparks and static discharge.

Risks of explosion of the product in presence of mechanical impact:
Slightly explosive in presence of shocks.
Fire Fighting Media
and Instructions
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire)
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Be sure to use an approved/certified respirator or equivalent.
Special Remarks on Fire Hazards
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Combustible solid.
Special Remarks on Explosion Hazards
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Potentially explosive reaction with metal nitrates. (Citric Acid, Anhydrous)
Solvent Spill Kit, SpillSolv ® Fine dust clouds may form explosive mixtures with air.

Section 6. Accidental Release Measures
Small Spill and Leak
Acid Spill Kit, SpillSolv ® Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Caustic Spill Kit, SpillSolv ® Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Solvent Spill Kit, SpillSolv ® Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill and Leak
Acid Spill Kit, SpillSolv ® Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Caustic Spill Kit, SpillSolv ® Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Solvent Spill Kit, SpillSolv ® Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Spill Kit Information No specific spill kit required for this product.

Section 7. Handling and Storage
Handling
Acid Spill Kit, SpillSolv ® Do not get in eyes, on skin or on clothing. Do not ingest. Avoid breathing dust. Keep container closed.
Caustic Spill Kit, SpillSolv ® Avoid breathing dust. Keep container closed. Do not ingest. Do not get in eyes, on skin or on clothing.
Solvent Spill Kit, SpillSolv ® Avoid contact with eyes. Avoid breathing dust. Keep container closed. Do not ingest.
Storage
Acid Spill Kit, SpillSolv ® Keep container in a cool, well-ventilated area.
Caustic Spill Kit, SpillSolv ® Keep container in a cool, well-ventilated area.
Solvent Spill Kit, SpillSolv ® Keep container in a cool, well-ventilated area.

Section 8. Exposure Controls/Personal Protection
Engineering Controls
Acid Spill Kit, SpillSolv ® Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Caustic Spill Kit, SpillSolv ® Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Solvent Spill Kit, SpillSolv ® Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection
Eyes
Acid Spill Kit, SpillSolv ® Splash goggles.
Caustic Spill Kit, SpillSolv ® Splash goggles.
Solvent Spill Kit, SpillSolv ® Splash goggles.
Body
Acid Spill Kit, SpillSolv ® Lab coat.
Caustic Spill Kit, SpillSolv ® Lab coat.
Solvent Spill Kit, SpillSolv ® Lab coat.
Respiratory
Acid Spill Kit, SpillSolv ® Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate.
Caustic Spill Kit, SpillSolv ® Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate.
Solvent Spill Kit, SpillSolv ® Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Hands
Acid Spill Kit, SpillSolv ® Gloves.
Caustic Spill Kit, SpillSolv ® Gloves.
Solvent Spill Kit, SpillSolv ® Gloves.
Feet
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Not applicable.
Protective Clothing (Pictograms)
Splash goggles Lab coat Vapor Respirator Gloves
Personal Protection in Case of a Large Spill
Acid Spill Kit, SpillSolv ® Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Caustic Spill Kit, SpillSolv ® Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Solvent Spill Kit, SpillSolv ® Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
Sodium Carbonate, Anhydrous Not available.
Citric Acid, Anhydrous Not available.
Charcoal AUVA (Austria, 1995).
TWA: 6 mg/m3 8 hour(s). Form:
MAK-Werte Liste (Germany, 1998).
TWA: 1.5 mg/m3 8 hour(s). Form:
NAOSH (Ireland, 1999).
OEL: 4 mg/m3 8 hour(s). Form:
OEL: 10 mg/m3 8 hour(s). Form:
Ministry of Labour (KR, 1997).
TWA: 10 mg/m3 8 hour(s).

Section 9. Physical and Chemical Properties
Odor
Acid Spill Kit, SpillSolv ® Odorless.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Odorless.
Color
Acid Spill Kit, SpillSolv ® Pink.
Caustic Spill Kit, SpillSolv ® Colorless to light yellow.
Solvent Spill Kit, SpillSolv ® Black.
Physical State and Appearance
Acid Spill Kit, SpillSolv ® Solid. (Powder.)
Caustic Spill Kit, SpillSolv ® Solid. (Powder.)
Solvent Spill Kit, SpillSolv ® Solid.
Molecular Weight
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® Not applicable.
Molecular Formula
Acid Spill Kit, SpillSolv ® Not applicable.
Caustic Spill Kit, SpillSolv ® Not applicable.
Solvent Spill Kit, SpillSolv ® C
pH
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not applicable.
Boiling/Condensation Point
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Melting/Freezing Point
Acid Spill Kit, SpillSolv ® 851.06°C (1563.9°F) based on data for: Sodium Carbonate, Anhydrous.
Caustic Spill Kit, SpillSolv ® 152.9°C (307.2°F) based on data for: Citric Acid, Anhydrous.
Solvent Spill Kit, SpillSolv ® Sublimation temperature: 3650.05°C (6602.1°F)
Critical Temperature
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Specific Gravity
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® The only known value is 1.54 (Water = 1) (Citric Acid, Anhydrous).
Solvent Spill Kit, SpillSolv ® 1.5 (Water = 1)
Vapor Pressure
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Vapor Density
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Volatility
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Odor Threshold
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Evaporation Rate
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
VOC
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Viscosity
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
LogKow
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Ionicity (in Water)
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Solubility
Acid Spill Kit, SpillSolv ® Soluble in water.
Caustic Spill Kit, SpillSolv ® Soluble in water.
Solvent Spill Kit, SpillSolv ® Insoluble in water.
Physical Chemical Comments
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.

Section 10. Stability and Reactivity
Stability and Reactivity
Acid Spill Kit, SpillSolv ® The product is stable.
Caustic Spill Kit, SpillSolv ® The product is stable.
Solvent Spill Kit, SpillSolv ® The product is stable.
Conditions of Instability
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Incompatibility with Various Substances
Acid Spill Kit, SpillSolv ® Highly reactive with acids.
Caustic Spill Kit, SpillSolv ® Reactive with alkalis.
Solvent Spill Kit, SpillSolv ® Reactive with oxidizing agents.
Rem/Incompatibility
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Metal nitrates (Citric Acid, Anhydrous)
Solvent Spill Kit, SpillSolv ® Not available.
Hazardous Decomposition Products
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Hazardous Polymerization
Acid Spill Kit, SpillSolv ® Will not occur.
Caustic Spill Kit, SpillSolv ® Will not occur.
Solvent Spill Kit, SpillSolv ® Will not occur.

Section 11. Toxicological Information
RTECS Number:
Sodium Carbonate VZ4050000
Citric Acid, Anhydrous GE7350000
Charcoal FF5250100
Toxicity
Acid Spill Kit, SpillSolv ® Acute oral toxicity (LD50): 5113 mg/kg (Rat) (Calculated value for the mixture).
Acute toxicity of the vapor (LC50): 163 ppm 4 hours (Guinea pig) (Calculated value for the mixture).
Caustic Spill Kit, SpillSolv ® Acute oral toxicity (LD50): 6300 mg/kg (Mouse) (Calculated value for the mixture).
Solvent Spill Kit, SpillSolv ® LD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Acute Effects on Humans
Acid Spill Kit, SpillSolv ® Extremely hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Hazardous in case of inhalation (lung irritant). May be hazardous in case of ingestion.
Caustic Spill Kit, SpillSolv ® Extremely hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Hazardous in case of inhalation (lung irritant).
Solvent Spill Kit, SpillSolv ® May be hazardous in case of eye contact (irritant). May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. May be hazardous in case of inhalation (lung irritant).
Special Remarks on Toxicity
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Special Remarks on Chronic Effects on Humans
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Special Remarks on Other Toxic Effects on Humans
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Synergetic Products (Toxicologically)
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Irritancy
Acid Spill Kit, SpillSolv ® Draize Test: Not available.
Caustic Spill Kit, SpillSolv ® Draize Test: Not available.
Solvent Spill Kit, SpillSolv ® Draize Test: Not available.
Sensitization
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Carcinogenic Effects
Acid Spill Kit, SpillSolv ® This material is not known to cause cancer in animals or humans.
Caustic Spill Kit, SpillSolv ® This material is not known to cause cancer in animals or humans.
Solvent Spill Kit, SpillSolv ® This material is not known to cause cancer in animals or humans.
Toxicity to Reproductive System
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Teratogenic Effects
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Mutagenic Effects
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.

Section 12. Ecological Information
Ecotoxicity
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
BOD5 and COD
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Biodegradable/OECD
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Mobility
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.
Acid Spill Kit, SpillSolv ® Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Caustic Spill Kit, SpillSolv ® Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Solvent Spill Kit, SpillSolv ® Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation
Acid Spill Kit, SpillSolv ® The products of degradation are less toxic than the product itself.
Caustic Spill Kit, SpillSolv ® The product itself and its products of degradation are not toxic.
Solvent Spill Kit, SpillSolv ® The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® Not available.

Section 13. Disposal Considerations
EPA Waste Number
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Not available.
Solvent Spill Kit, SpillSolv ® D001
Treatment
Acid Spill Kit, SpillSolv ® Material does not have an EPA Waste Number and is not a listed waste, however consultation with a permitted waste disposal site (TSD) should be accomplished. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations.
Caustic Spill Kit, SpillSolv ® Material does not have an EPA Waste Number and is not a listed waste, however consultation with a permitted waste disposal site (TSD) should be accomplished. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations.
Solvent Spill Kit, SpillSolv ® Specified Technology - Thermal destruction. Contact your local permitted waste disposal (TSD) for permissible treatment sites. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations.

Section 14. Transport Information
DOT Classification Proper Shipping Name: CHEMICALS, N.O.S.
RQ: Not applicable.
TDG Classification Not available.
IMO/IMDG Classification Proper Shipping Name: CHEMICALS, N.O.S.
RQ: Not applicable.
ICAO/IATA Classification Not available.

Section 15. Regulatory Information
U.S. Federal Regulations
Acid Spill Kit, SpillSolv ® TSCA 8(b) inventory: SODIUM CARBONATE, ANHYDROUS
Additional nonhazardous components (not disclosed by the manufacturer) are on the TSCA Inventory.
Caustic Spill Kit, SpillSolv ® TSCA 8(b) inventory: CITRIC ACID, ANHYDROUS
Additional nonhazardous components (not disclosed by the manufacturer) are on the TSCA Inventory.
Solvent Spill Kit, SpillSolv ® TSCA 8(b) inventory: Charcoal
Additional nonhazardous components (not disclosed by the manufacturer) are on the TSCA Inventory.
Acid Spill Kit, SpillSolv ® SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Sodium Carbonate, Anhydrous
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Sodium Carbonate, Anhydrous: Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard
Caustic Spill Kit, SpillSolv ® SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Citric Acid, Anhydrous
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Citric Acid, Anhydrous: Immediate (Acute) Health Hazard
Solvent Spill Kit, SpillSolv ® SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Charcoal
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Charcoal: Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard
Acid Spill Kit, SpillSolv ® SARA 313 toxic chemical notification and release reporting: No products were found.
Caustic Spill Kit, SpillSolv ® SARA 313 toxic chemical notification and release reporting: No products were found.
Solvent Spill Kit, SpillSolv ® SARA 313 toxic chemical notification and release reporting: No products were found.
Acid Spill Kit, SpillSolv ® Clean Water Act (CWA) 307: No products were found.
Caustic Spill Kit, SpillSolv ® Clean Water Act (CWA) 307: No products were found.
Solvent Spill Kit, SpillSolv ® Clean Water Act (CWA) 307: No products were found.
Acid Spill Kit, SpillSolv ® Clean Water Act (CWA) 311: No products were found.
Caustic Spill Kit, SpillSolv ® Clean Water Act (CWA) 311: No products were found.
Solvent Spill Kit, SpillSolv ® Clean Water Act (CWA) 311: No products were found.
Acid Spill Kit, SpillSolv ® Clean air act (CAA) 112 accidental release prevention: No products were found.
Caustic Spill Kit, SpillSolv ® Clean air act (CAA) 112 accidental release prevention: No products were found.
Solvent Spill Kit, SpillSolv ® Clean air act (CAA) 112 accidental release prevention: No products were found.
Acid Spill Kit, SpillSolv ® Clean air act (CAA) 112 regulated flammable substances: No products were found.
Caustic Spill Kit, SpillSolv ® Clean air act (CAA) 112 regulated flammable substances: No products were found.
Solvent Spill Kit, SpillSolv ® Clean air act (CAA) 112 regulated flammable substances: No products were found.
Acid Spill Kit, SpillSolv ® Clean air act (CAA) 112 regulated toxic substances: No products were found.
Caustic Spill Kit, SpillSolv ® Clean air act (CAA) 112 regulated toxic substances: No products were found.
Solvent Spill Kit, SpillSolv ® Clean air act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada)
Acid Spill Kit, SpillSolv ® Not available.
Caustic Spill Kit, SpillSolv ® Class D-2B: Material causing other toxic effects (TOXIC).
Solvent Spill Kit, SpillSolv ® Not controlled under WHMIS (Canada).
Acid Spill Kit, SpillSolv ® CEPA DSL: Sodium Carbonate, Anhydrous
Caustic Spill Kit, SpillSolv ® CEPA DSL: Citric Acid, Anhydrous
Solvent Spill Kit, SpillSolv ® CEPA DSL: Charcoal
This product has been classifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information.
International Regulations
EINECS Sodium Carbonate, Anhydrous 207-838-8
Citric Acid, Anhydrous 201-069-1
Charcoal 231-153-3
DSCL (EEC)
Acid Spill Kit, SpillSolv ® R37/38- Irritating to respiratory system and skin.
R41- Risk of serious damage to eyes.
Caustic Spill Kit, SpillSolv ® R37/38- Irritating to respiratory system and skin.
R41- Risk of serious damage to eyes.
Solvent Spill Kit, SpillSolv ® R11- Highly flammable.
R36/37- Irritating to eyes and respiratory system.
International Lists
Acid Spill Kit, SpillSolv ® Australia (NICNAS): Sodium Carbonate, Anhydrous

Japan (MITI): Sodium Carbonate, Anhydrous

Korea (TCCL): Sodium Carbonate, Anhydrous

Philippines (RA6969): Sodium Carbonate, Anhydrous
Caustic Spill Kit, SpillSolv ® Australia (NICNAS): Citric Acid, Anhydrous

Japan (MITI): Citric Acid, Anhydrous

Korea (TCCL): Citric Acid, Anhydrous

Philippines (RA6969): Citric Acid, Anhydrous
Solvent Spill Kit, SpillSolv ® Australia (NICNAS): Charcoal

Germany water class: Charcoal

Korea (TCCL): Charcoal

Philippines (RA6969): Charcoal
China: No products were found.
State Regulations
Acid Spill Kit, SpillSolv ® No products were found.
Caustic Spill Kit, SpillSolv ® No products were found.
Solvent Spill Kit, SpillSolv ® No products were found.
Acid Spill Kit, SpillSolv ® California prop. 65: No products were found.
Caustic Spill Kit, SpillSolv ® California prop. 65: No products were found.
Solvent Spill Kit, SpillSolv ® California prop. 65: No products were found.

Section 16. Other Information
National Fire Protection Association (U.S.A.)
1

Health		 2
0
Fire Hazard

Reactivity
Specific Hazard
Other Special Considerations
Acid Spill Kit, SpillSolv ® Contains additional nonhazardous component(s) not released by the manufacturer.
Caustic Spill Kit, SpillSolv ® Contains additional nonhazardous component(s) not released by the manufacturer.
Solvent Spill Kit, SpillSolv ® Contains additional nonhazardous component(s) not released by the manufacturer.
Changed Since Last Revision +
Notice to Reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.