Material Safety Data Sheet
+ Section 1. Product and Company Identification
Product Name EDTA di-Sodium Dihydrate Product Code 4050
Manufacturer
EMD Chemicals Inc.
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
Prior to January 1, 2003 EMD Chemicals Inc. was EM Industries, Inc. or EM Science, Division of EM Industries, Inc.
Effective Date
3/4/2003
For More Information Call In Case of Emergency Call
856-423-6300 Technical Service
Monday-Friday: 8:00 AM - 5:00 PM
800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Synonym None.
Material Uses Analytical reagent.
Chemical Family Organic Salt


Section 2. Composition and Information on Ingredients
Component CAS # % by Weight
EDTA di-Sodium Dihydrate 6381-92-6 100


+ Section 3. Hazards Identification
Physical State and Appearance Solid. (Crystalline powder)
Emergency Overview WARNING !
HARMFUL IF INHALED OR SWALLOWED.
MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
Routes of Entry Eye contact. Inhalation. Ingestion.
Potential Acute Health Effects
Eyes May be hazardous in case of eye contact (irritant).
Skin May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Inhalation Hazardous in case of inhalation. May be hazardous in case of inhalation (lung irritant).
Ingestion Hazardous in case of ingestion.
Potential Chronic Health Effects
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
Additional information See Toxicological Information (section 11)
Medical Conditions Aggravated by Overexposure: Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.


Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.


+ Section 5. Fire Fighting Measures
Flammability of the Product Non-flammable.
Auto-ignition Temperature Not applicable.
Flash Points Not applicable.
Flammable Limits Not applicable.
Products of Combustion Not applicable.
Fire Hazards in Presence of Various Substances Not applicable.
Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of static discharge: No.

Risks of explosion of the product in presence of mechanical impact: No.
Fire Fighting Media
and Instructions
Not applicable.
Protective Clothing (Fire) Not applicable.
Special Remarks on Fire Hazards Not available.
Special Remarks on Explosion Hazards May emit toxic fumes under fire conditions.
Thermal decomposition may release toxic and/or hazardous gases.


Section 6. Accidental Release Measures
Small Spill and Leak Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill and Leak Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Spill Kit Information No specific spill kit required for this product.


Section 7. Handling and Storage
Handling Avoid contact with eyes, skin and clothing. Do not ingest. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.


Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection
Eyes Splash goggles.
Body Lab coat.
Respiratory Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Hands Gloves.
Feet Not applicable.
Protective Clothing (Pictograms)
Splash goggles Lab coat Dust Respirator Gloves
Personal Protection in Case of a Large Spill Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
EDTA di-Sodium Dihydrate Not available.


+ Section 9. Physical and Chemical Properties
Odor Odorless.
Color White.
Physical State and Appearance Solid. (Crystalline powder)
Molecular Weight 372.24 g/mole
Molecular Formula C10H14N2Na2O8*2H2O
pH Not available.
Boiling/Condensation Point Not available.
Melting/Freezing Point 248°C (478.4°F)
Specific Gravity Not available.
Vapor Pressure Not available.
Vapor Density Not available.
Odor Threshold Not available.
Evaporation Rate Not available.
LogKow Not available.
Solubility Soluble in water.


+ Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Conditions of Instability Not available.
Incompatibility with Various Substances Reactive with oxidizing agents, metals.
Rem/Incompatibility Avoid generating dust or vapors. Extreme heat
Hazardous Decomposition Products NOx
Hazardous Polymerization Will not occur.


Section 11. Toxicological Information
RTECS Number:
EDTA di-Sodium Dihydrate Not available.
Toxicity Acute oral toxicity (LD50): 2000 mg/kg [Rat].
Chronic Effects on Humans Not available.
Acute Effects on Humans May be hazardous in case of eye contact (irritant). May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Hazardous in case of inhalation (lung irritant). Extremely hazardous in case of ingestion. May be fatal if swallowed.
Synergetic Products (Toxicologically) Not available.
Irritancy Draize Test: Not available.
Sensitization Not available.
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
Toxicity to Reproductive System Not available.
Teratogenic Effects Not available.
Mutagenic Effects Not available.


Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Toxicity of the Products of Biodegradation The products of degradation are less toxic than the product itself.


Section 13. Disposal Considerations
EPA Waste Number Not available.
Treatment Material does not have an EPA Waste number and is not a listed waste, however consultation with a permitted waste disposal site (TSD) should be accomplished.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.


Section 14. Transport Information
DOT Classification Proper Shipping Name: CHEMICALS, N.O.S.
RQ: Not applicable.
TDG Classification Not available.
IMO/IMDG Classification Proper Shipping Name: CHEMICALS, N.O.S.
RQ: Not applicable.
ICAO/IATA Classification Not available.


Section 15. Regulatory Information
U.S. Federal Regulations TSCA 8(b) inventory: EDTA di-Sodium Dihydrate
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada) Class D-2B: Material causing other toxic effects (TOXIC).
No products were found.
This product has been classiifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information.
International Regulations
EINECS EDTA di-Sodium Dihydrate 205-358-3
DSCL (EEC) R22- Harmful if swallowed.
R36/37/38- Irritating to eyes, respiratory system and skin.
International Lists No products were found.
China: No products were found.
State Regulations New Jersey: EDTA di-Sodium Dihydrate
California prop. 65: No products were found.


Section 16. Other Information
National Fire Protection Association (U.S.A.)


Health
1
1 0
Fire Hazard

Reactivity

Specific Hazard
Changed Since Last Revision +
Notice to Reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.