| Section 1. Product and Company Identification |
| Product Name | Product Code | BX1735-30 |
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| For More Information Call | In Case of Emergency Call |
| 856-423-6300 Technical Service
Monday-Friday: 8:00 AM - 5:00 PM |
800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada) 24 Hours/Day: 7 Days/Week |
| Synonym | N-1-BUTYL ETHANOATE |
| Material Uses | Analytical reagent.
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| Chemical Family | Ester. |
| Section 2. Composition and Information on Ingredients |
| Component | CAS # | % by Weight |
| BUTYL ACETATE | 123-86-4 | 100 |
| Section 3. Hazards Identification |
| Physical State and Appearance | Liquid. |
| Emergency Overview | DANGER!
FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF INHALED OR SWALLOWED. CAUSES SEVERE EYE IRRITATION. CAUSES RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: RESPIRATORY TRACT, SKIN, EYES, CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA. |
| Routes of Entry | Inhalation. Ingestion. |
| Potential Acute Health Effects |
| Eyes | Extremely hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching. |
| Skin | Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Non-permeator by skin. |
| Inhalation | Hazardous in case of inhalation (lung irritant). |
| Ingestion | Hazardous in case of ingestion. |
| Potential Chronic Health Effects |
| Carcinogenic Effects | This material is not known to cause cancer in animals or humans. |
| Additional information See Toxicological Information (section 11) |
| Medical Conditions Aggravated by Overexposure: | Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. |
| Section 4. First Aid Measures |
| Eye Contact | Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention immediately. |
| Skin Contact | In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. |
| Inhalation | If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. |
| Ingestion | If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. |
| Section 5. Fire Fighting Measures |
| Flammability of the Product | Product will burn. |
| Auto-ignition Temperature | 420.9°C (789.6°F) |
| Flash Points | Closed cup: 21.9°C (71.4°F). |
| Flammable Limits | LOWER: 1.7% UPPER: 7.6% |
| Products of Combustion | These products are carbon oxides (CO, CO2). |
| Fire Hazards in Presence of Various Substances | Highly flammable in presence of open flames, sparks and static discharge, of heat, of oxidizing materials. |
| Explosion Hazards in Presence of Various Substances | Risks of explosion of the product in presence of static discharge:
Highly flammable in presence of open flames, sparks and static discharge. Risks of explosion of the product in presence of mechanical impact: No. |
| Fire Fighting Media
and Instructions |
Flammable liquid, soluble or dispersed in water.
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion. |
| Protective Clothing (Fire) | Be sure to use an approved/certified respirator or equivalent. |
| Special Remarks on Fire Hazards | Vapor may travel considerable distance to source of ignition and flash back. |
| Special Remarks on Explosion Hazards | Not available. |
| Section 6. Accidental Release Measures |
| Small Spill and Leak | Absorb with an inert material and put the spilled material in an appropriate waste disposal. |
| Large Spill and Leak | Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. |
| Spill Kit Information | The following EMD Chemicals Inc. SpillSolv ® absorbent is recommended for this product: SX1330 Solvent Treatment Kit |
| Section 7. Handling and Storage |
| Handling | Keep away from heat, sparks and flame. Keep container closed. Do not get in eyes, on skin, or on clothing. Do not ingest. Avoid breathing vapors or spray mists. |
| Storage | Keep container in a cool, well-ventilated area. |
| Section 8. Exposure Controls/Personal Protection |
| Engineering Controls | Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. |
| Personal Protection |
| Eyes | Splash goggles. |
| Body | Lab coat. |
| Respiratory | Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. |
| Hands | Gloves. |
| Feet | Not applicable. |
| Protective Clothing (Pictograms) |
| Personal Protection in Case of a Large Spill | Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. |
| Product Name | Exposure Limits |
| BUTYL ACETATE | AUVA (Austria, 1995).
PEAK: 1400 mg/m3 8 times per shift, Period: 5 minute(s). PEAK: 300 ppm 8 times per shift, Period: 5 minute(s). MAK: 700 mg/m3 MAK: 150 ppm Belgium Minister of Labour (Belgium, 1998). VCD: 964 mg/m3 VCD: 200 ppm VL: 723 mg/m3 VL: 150 ppm BAUA (Germany, 1997). PEAK: 950 mg/m3 PEAK: 200 ppm MAK: 950 mg/m3 MAK: 200 ppm DK-Arbejdstylsinet (Denmark, 1996). GV: 710 mg/m3 GV: 150 ppm Tyterveyslaitos (Finland, 1998). STEL: 960 mg/m3 STEL: 200 ppm TWA: 720 mg/m3 TWA: 150 ppm INRS (France, 1996). VLE: 940 mg/m3 VLE: 200 ppm VME: 710 mg/m3 VME: 150 ppm National Authority for Occupational Safety/Health (Ireland, 1999). STEL: 950 mg/m3 STEL: 200 ppm OEL: 710 mg/m3 OEL: 150 ppm Arbeidsinspectie (Netherlands, 1999). TGG 8 uur: 710 mg/m3 TGG 8 uur: 150 ppm N-Arbeidstylsinet (Norway, 1996). AN: 355 mg/m3 AN: 75 ppm EH40-OES (United Kingdom (UK), 1997). STEL: 966 mg/m3 STEL: 200 ppm MEL: 724 mg/m3 MEL: 150 ppm ACGIH (United States, 1998). STEL: 200 ppm TWA: 150 ppm NIOSH REL (United States, 1994). STEL: 950 mg/m3 STEL: 200 ppm TWA: 710 mg/m3 Period: 10 hour(s). TWA: 150 ppm Period: 10 hour(s). OSHA Final Rule (United States, 1989). STEL: 950 mg/m3 STEL: 200 ppm TWA: 710 mg/m3 TWA: 150 ppm |
| Section 9. Physical and Chemical Properties |
| Odor | Fruity. |
| Color | Colorless. |
| Physical State and Appearance | Liquid. |
| Molecular Weight | 116.18 g/mole |
| Molecular Formula | C6-H12-O2 |
| pH | Not available. |
| Boiling/Condensation Point | 126.3°C (259.3°F) |
| Melting/Freezing Point | -75°C (-103°F) |
| Critical Temperature | 306°C (582.8°F) |
| Specific Gravity | 0.875 (Water = 1) |
| Vapor Pressure | Not available. |
| Vapor Density | 4 (Air = 1) |
| Odor Threshold | 10 ppm |
| Evaporation Rate | 1 compared to (n-BUTYL ACETATE=1) |
| LogKow | Not available. |
| Solubility | Very slightly soluble in water. |
| Section 10. Stability and Reactivity |
| Stability and Reactivity | The product is stable. |
| Conditions of Instability | Not available. |
| Incompatibility with Various Substances | Highly reactive with oxidizing agents.
Reactive with acids, alkalis. |
| Rem/Incompatibility | Not available. |
| Hazardous Decomposition Products | Not available. |
| Hazardous Polymerization | Will not occur. |
| Section 11. Toxicological Information |
| RTECS Number: |
| Butyl Acetate | AF7350000 |
| Toxicity | Acute oral toxicity (LD50): 3200 mg/kg [Rabbit].
Acute dermal toxicity (LD50): >17600 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 2000 ppm 4 hour(s) [Rat]. |
| Chronic Effects on Humans | Not available. |
| Acute Effects on Humans | Extremely hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Non-permeator by skin. Hazardous in case of inhalation (lung irritant). Hazardous in case of ingestion. |
| Synergetic Products (Toxicologically) | Not available. |
| Irritancy | Draize Test (Rabbit):
Skin: 500mg/24h. Reaction: Moderate. |
| Sensitization | Not available. |
| Carcinogenic Effects | This material is not known to cause cancer in animals or humans. |
| Toxicity to Reproductive System | Tests on laboratory animals for reproductive effects are cited in Registry of Toxic Effects on Chemical Substances (RTECS). |
| Teratogenic Effects | Not available. |
| Mutagenic Effects | Not available. |
| Section 12. Ecological Information |
| Ecotoxicity | Not available. |
| BOD5 and COD | Not available. |
| Toxicity of the Products of Biodegradation | The products of degradation are less toxic than the product itself. |
| Section 13. Disposal Considerations |
| EPA Waste Number | D001 |
| Treatment | Incineration, fuels blending or recycle. Contact your local permitted waste disposal site (TSD) for permissible treatment sites. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations. |
| Section 14. Transport Information |
| DOT Classification | Proper Shipping Name: BUTYL ACETATE
Hazard Class: 3 UN number: UN1123 Packing Group: II RQ: 5000 lbs. (2268 kg) |
| TDG Classification | Not available. |
| IMO/IMDG Classification | Proper Shipping Name: BUTYL ACETATE
Hazard Class: 3 UN number: UN1123 Packing Group: II RQ: 5000 |
| ICAO/IATA Classification | Not available. |
| Section 15. Regulatory Information |
| U.S. Federal Regulations | TSCA 4(a) final test rules: BUTYL ACETATE
TSCA 8(b) inventory: BUTYL ACETATE TSCA 12(b) one time export: BUTYL ACETATE |
| SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: BUTYL ACETATE SARA 311/312 MSDS distribution - chemical inventory - hazard identification: BUTYL ACETATE: Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard |
| SARA 313 toxic chemical notification and release reporting: No products were found. |
| Clean Water Act (CWA) 307: No products were found. |
| Clean Water Act (CWA) 311: BUTYL ACETATE |
| Clean air act (CAA) 112 accidental release prevention: No products were found. |
| Clean air act (CAA) 112 regulated flammable substances: No products were found. |
| Clean air act (CAA) 112 regulated toxic substances: No products were found. |
| WHMIS (Canada) | CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).
Class D-1B: Material causing immediate and serious toxic effects (TOXIC). Class D-2B: Material causing other toxic effects (TOXIC). |
| CEPA DSL: BUTYL ACETATE |
| This product has been classiifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information. |
| International Regulations |
| EINECS | BUTYL ACETATE 204-658-1 |
| DSCL (EEC) | R10- Flammable. |
| International Lists | Australia (NICNAS): BUTYL ACETATE
Japan (MITI): BUTYL ACETATE Japan (MOL): BUTYL ACETATE Korea (TCCL): BUTYL ACETATE Philippines (RA6969): BUTYL ACETATE |
| China: No products were found. |
| State Regulations | Pennsylvania RTK: BUTYL ACETATE: (environmental hazard, generic environmental hazard)
Massachusetts RTK: BUTYL ACETATE New Jersey: BUTYL ACETATE |
| California prop. 65: No products were found. |
| Section 16. Other Information |
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| Changed Since Last Revision | + |
| Notice to Reader |
| The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. |