| Iron (II) fumarate extra pure (ca. 33% Fe) USP, Ph Eur, BP,FCC | 1.03962 | Page: 1/1 |
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| Section 1. Product and Company Identification |
| Product Name | Iron (II) fumarate extra pure (ca. 33% Fe) USP, Ph Eur, BP,FCC | Product Code | 1.03962 |
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| For More Information Call | In Case of Emergency Call |
| (914) 592-4660
M-F, 9AM-4:30 PM EST |
800-424-9300 CHEMTREC (USA)
613-996-6666 (Canada) 24 Hours/Day: 7 Days/Week |
| Synonym | 2-butenedioic acid (e)-, iron(2+) salt (1:1) |
| Material Uses | Analytical reagent.
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| Chemical Family | Salt. |
| Section 2. Composition and Information on Ingredients |
| Component | CAS # | % by Weight |
| Iron (II) fumarate | 141-01-5 | 100 |
| Section 3. Hazards Identification |
| Physical State and Appearance | Solid. (Powder.) |
| Emergency Overview | CAUTION !
MAY CAUSE EYE AND SKIN IRRITATION. |
| Routes of Entry | Dermal contact. Eye contact. |
| Potential Acute Health Effects |
| Eyes | May be hazardous in case of eye contact (irritant). |
| Skin | May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. |
| Inhalation | No known acute effects of this product resulting from inhalation. |
| Ingestion | No known acute effects of this product resulting from ingestion. |
| Potential Chronic Health Effects |
| Carcinogenic Effects | This material is not known to cause cancer in animals or humans. |
| Additional information See Toxicological Information (section 11) |
| Medical Conditions Aggravated by Overexposure: | Repeated or prolonged exposure is not known to aggravate medical condition. |
| Section 4. First Aid Measures |
| Eye Contact | Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. |
| Skin Contact | In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. |
| Inhalation | If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. |
| Ingestion | Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. |
| Section 5. Fire Fighting Measures |
| Flammability of the Product | Non-flammable. |
| Auto-ignition Temperature | Not applicable. |
| Flash Points | Not applicable. |
| Flammable Limits | Not applicable. |
| Products of Combustion | Not applicable. |
| Fire Hazards in Presence of Various Substances | Not applicable. |
| Explosion Hazards in Presence of Various Substances | Risks of explosion of the product in presence of static discharge: No.
Risks of explosion of the product in presence of mechanical impact: No. |
| Fire Fighting Media
and Instructions |
Not applicable. |
| Protective Clothing (Fire) | Wear suitable protective clothing. |
| Special Remarks on Fire Hazards | Not available. |
| Special Remarks on Explosion Hazards | Forms explosive mixtures in air. |
| Section 6. Accidental Release Measures |
| Small Spill and Leak | Use appropriate tools to put the spilled solid in a convenient waste disposal container. |
| Large Spill and Leak | Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. |
| Spill Kit Information | No specific spill kit required for this product. |
| Section 7. Handling and Storage |
| Handling | Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. |
| Storage | Keep container tightly closed. Keep container in a cool, well-ventilated area. Store between 15 to 25°C (59 to 77°F). |
| Section 8. Exposure Controls/Personal Protection |
| Engineering Controls | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Personal Protection |
| Eyes | Splash goggles. |
| Body | Lab coat. |
| Respiratory | Dust respirator. Be sure to use an approved/certified respirator or equivalent. |
| Hands | Gloves. |
| Feet | Not applicable. |
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| Personal Protection in Case of a Large Spill | Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. |
| Product Name | Exposure Limits |
| Iron (II) fumarate | Lijst Grenswaarden (Belgium, 2002).
VL: 1 mg/m3 8 hour(s). SUVA (Switzerland, 2001). MAK: 1 mg/m3 8 hour(s). Form: Dust Arbejdstilsynet (Denmark, 2000). GV: 1 mg/m3 8 hour(s). INSHT (Spain, 2001). TWA: 1 mg/m3 8 hour(s). Työterveyslaitos (Finland, 2002). TWA: 1 mg/m3 8 hour(s). NAOSH (Ireland, 2002). STEL: 2 mg/m3 15 minute(s). OEL: 1 mg/m3 8 hour(s). Nationale MAC-lijst (Netherlands, 2003). Notes: Administrative TGG 8 uur: 1 mg/m3 8 hour(s). Arbeidstilsynet (Norway, 2001). AN: 1 mg/m3 8 hour(s). EH40-OES (United Kingdom (UK), 2002). STEL: 2 mg/m3 15 minute(s). TWA: 1 mg/m3 8 hour(s). ACGIH TLV (United States, 2002). TWA: 1 mg/m3 8 hour(s). NIOSH REL (United States, 2001). TWA: 1 mg/m3 10 hour(s). Form: Soluble OSHA PEL 1989 (United States, 1989). TWA: 1 mg/m3 8 hour(s). Form: Soluble |
| Section 9. Physical and Chemical Properties |
| Odor | Odorless. |
| Color | Reddish-brown |
| Physical State and Appearance | Solid. (Powder.) |
| Molecular Weight | 169.9 g/mole |
| Molecular Formula | C4H2FeO4 |
| pH | Not available. |
| Boiling/Condensation Point | Not available. |
| Melting/Freezing Point | >280°C (536°F) |
| Specific Gravity | Not available. |
| Vapor Pressure | Not available. |
| Vapor Density | Not available. |
| Odor Threshold | Not available. |
| Evaporation Rate | Not available. |
| LogKow | Not available. |
| Solubility | Very slightly soluble in water. |
| Section 10. Stability and Reactivity |
| Stability and Reactivity | The product is stable. |
| Conditions of Instability | Not available. |
| Incompatibility with Various Substances | Not available. |
| Rem/Incompatibility | Not available. |
| Hazardous Decomposition Products | Oxides of carbon. |
| Hazardous Polymerization | Will not occur. |
| Section 11. Toxicological Information |
| RTECS Number: |
| Iron (II) fumarate | LT1950000 |
| Toxicity | Acute oral toxicity (LD50): 1570 mg/kg [Mouse]. |
| Chronic Effects on Humans | Not available. |
| Acute Effects on Humans | May be hazardous in case of eye contact (irritant). May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Non-hazardous in the case of ingestion. |
| Synergetic Products (Toxicologically) | Not available. |
| Irritancy | Draize Test: Not available. |
| Sensitization | Not available. |
| Carcinogenic Effects | This material is not known to cause cancer in animals or humans. |
| Toxicity to Reproductive System | Not available. |
| Teratogenic Effects | Not available. |
| Mutagenic Effects | Not available. |
| Section 12. Ecological Information |
| Ecotoxicity | Not available. |
| BOD5 and COD | Not available. |
| Toxicity of the Products of Biodegradation | The products of degradation are more toxic than the product itself. |
| Section 13. Disposal Considerations |
| EPA Waste Number | Not available. |
| Treatment | Material does not have an EPA Waste number and is not a listed waste, however consultation with a permitted waste disposal site (TSD) should be accomplished.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. |
| Section 14. Transport Information |
| DOT Classification | Not available. |
| TDG Classification | Not available. |
| IMO/IMDG Classification | Not available. |
| ICAO/IATA Classification | Not available. |
| Section 15. Regulatory Information |
| U.S. Federal Regulations | TSCA 8(b) inventory: Iron (II) fumarate |
| SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. |
| SARA 313 toxic chemical notification and release reporting: No products were found. |
| Clean Water Act (CWA) 307: No products were found. |
| Clean Water Act (CWA) 311: No products were found. |
| Clean air act (CAA) 112 accidental release prevention: No products were found. |
| Clean air act (CAA) 112 regulated flammable substances: No products were found. |
| Clean air act (CAA) 112 regulated toxic substances: No products were found. |
| WHMIS (Canada) | Not controlled under WHMIS (Canada). |
| CEPA DSL: Iron (II) fumarate |
| This product has been classifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information. |
| International Regulations |
| EINECS | Iron (II) fumarate 205-447-7 |
| DSCL (EEC) | R36/38- Irritating to eyes and skin. |
| International Lists | Australia (NICNAS): Iron (II) fumarate
China: Iron (II) fumarate Japan (MITI): Iron (II) fumarate Korea (TCCL): Iron (II) fumarate Philippines (RA6969): Iron (II) fumarate |
| China: Iron (II) fumarate |
| State Regulations | Pennsylvania RTK: Iron (II) fumarate: (environmental hazard, generic environmental hazard)
New Jersey: Iron (II) fumarate |
| California prop. 65: No products were found. |
| Section 16. Other Information |
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| Changed Since Last Revision | + |
| Notice to Reader |
| The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. |
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