Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name Oleic Acid Product Code 481
Manufacturer
EMD Chemicals Inc.
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
Prior to January 1, 2003 EMD Chemicals Inc. was EM Industries, Inc. or EM Science, Division of EM Industries, Inc.
Effective Date
3/3/2003
For More Information Call In Case of Emergency Call
856-423-6300 Technical Service
Monday-Friday: 8:00 AM - 5:00 PM
800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Synonym 9-OCTADECENOIC ACID
Material Uses Analytical reagent.
Chemical Family Monounsaturated fatty acid.


Section 2. Composition and Information on Ingredients
Component CAS # % by Weight
OLEIC ACID 112-80-1 100


Section 3. Hazards Identification
Physical State and Appearance Liquid. (Oily liquid.)
Emergency Overview CAUTION!
CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
Routes of Entry Inhalation. Ingestion.
Potential Acute Health Effects
Eyes Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching.
Skin Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Inhalation Hazardous in case of inhalation (lung irritant).
Ingestion Large quantities may cause nausea, upset stomach, loss of appetite.
Potential Chronic Health Effects
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
Additional information See Toxicological Information (section 11)
Medical Conditions Aggravated by Overexposure: Repeated or prolonged exposure is not known to aggravate medical condition.


Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.


Section 5. Fire Fighting Measures
Flammability of the Product May be combustible at high temperature.
Auto-ignition Temperature 361.9°C (683.4°F)
Flash Points Closed cup: 188.9°C (372°F).
Flammable Limits Not available.
Products of Combustion These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances Slightly flammable to flammable in presence of heat.
Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of static discharge: No.

Risks of explosion of the product in presence of mechanical impact: No.
Fire Fighting Media
and Instructions
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire) Be sure to use an approved/certified respirator or equivalent.
Special Remarks on Fire Hazards Not available.
Special Remarks on Explosion Hazards Not available.


Section 6. Accidental Release Measures
Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Spill Kit Information No specific spill kit required for this product.


Section 7. Handling and Storage
Handling Avoid breathing vapors or spray mists. Keep container closed. Do not get in eyes, on skin, or on clothing. Do not ingest.
Storage Keep container in a cool, well-ventilated area.


Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection
Eyes Splash goggles.
Body Lab coat.
Respiratory Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate.
Hands Gloves.
Feet Not applicable.
Protective Clothing (Pictograms)
Splash goggles Lab coat Vapor Respirator Gloves
Personal Protection in Case of a Large Spill Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
OLEIC ACID Not available.


Section 9. Physical and Chemical Properties
Odor Not available.
Color Colorless to light yellow.
Physical State and Appearance Liquid. (Oily liquid.)
Molecular Weight 282.52 g/mole
Molecular Formula C18-H34-O2
pH Not applicable.
Boiling/Condensation Point 285.9°C (546.6°F)
Melting/Freezing Point 13.9°C (57°F)
Specific Gravity 0.89 (Water = 1)
Vapor Pressure Not available.
Vapor Density Not available.
Odor Threshold Not available.
Evaporation Rate Not available.
LogKow Not available.
Solubility Insoluble in water.


Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Conditions of Instability Not available.
Incompatibility with Various Substances Reactive with oxidizing agents.
Rem/Incompatibility Not available.
Hazardous Decomposition Products Not available.
Hazardous Polymerization Will not occur.


Section 11. Toxicological Information
RTECS Number:
Oleic Acid RG2275000
Toxicity LD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Acute Effects on Humans Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Hazardous in case of inhalation (lung irritant).
Synergetic Products (Toxicologically) Not available.
Irritancy Draize Test ((Human)):
Skin: 15mg/3 Days. Reaction: Moderate.
Sensitization Not available.
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
Toxicity to Reproductive System Not available.
Teratogenic Effects Not available.
Mutagenic Effects Tests on laboratory animals for mutagenic effects are cited in Registry of Toxic Effects of Chemical Substances (RTECS).


Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Toxicity of the Products of Biodegradation The product itself and its products of degradation are not toxic.


Section 13. Disposal Considerations
EPA Waste Number Not available.
Treatment Material does not have an EPA Waste Number and is not a listed waste, however consultation with a permitted waste disposal site (TSD) should be accomplished. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations.


Section 14. Transport Information
DOT Classification Not available.
TDG Classification Not available.
IMO/IMDG Classification Not available.
ICAO/IATA Classification Not available.


Section 15. Regulatory Information
U.S. Federal Regulations TSCA 8(b) inventory: OLEIC ACID
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: OLEIC ACID
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: OLEIC ACID: Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada) Class D-2B: Material causing other toxic effects (TOXIC).
CEPA DSL: OLEIC ACID
This product has been classiifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information.
International Regulations
EINECS OLEIC ACID 204-007-1
DSCL (EEC) R37/38- Irritating to respiratory system and skin.
R41- Risk of serious damage to eyes.
International Lists Australia (NICNAS): OLEIC ACID

Japan (MITI): OLEIC ACID

Korea (TCCL): OLEIC ACID

Philippines (RA6969): OLEIC ACID
China: No products were found.
State Regulations Pennsylvania RTK: OLEIC ACID: (generic environmental hazard)
California prop. 65: No products were found.


Section 16. Other Information
National Fire Protection Association (U.S.A.)


Health
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Reactivity

Specific Hazard
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Notice to Reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.